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| Maria Sakkari - Cori Gauff | 16:05 | ||
| Zizou Bergs - Ben Shelton | 18:05 | ||
| Elise Mertens - Naomi Osaka | 19:00 | ||
| Botic Van De Zandschulp - Hubert Hurkacz | 18:05 | ||
| Mirra Andreeva - Leylah Annie Fernandez | 18:05 | ||
| Botic Van De Zandschulp - Hubert Hurkacz | 18:05 | ||
| Maria Sakkari - Cori Gauff | 16:05 | ||
| Mirra Andreeva - Leylah Annie Fernandez | 18:05 | ||
| Elise Mertens - Naomi Osaka | 19:00 | ||
| Tallon Griekspoor - Matteo Arnaldi | 16:35 | ||
| Zizou Bergs - Ben Shelton | 18:05 | ||
| Tallon Griekspoor - Matteo Arnaldi | 16:35 | ||
| all times GMT +2 | |||